Transmissive or reflective liquid crystal display and process for its manufacture

ABSTRACT

This invention relates to cholesteric liquid crystal (LC) displays comprising cells of well-defined shape, size and aspect ratio which cells are filled with a liquid crystal composition preferably containing dichroic dye(s), and novel processes for their manufacture.

This application is a continuation-in-part of U.S. application Ser. No.10/794,318, filed Mar. 5, 2004, which is a continuation-in-part of U.S.application Ser. No. 09/759,212, filed Jan. 11, 2001, both of which areincorporated herein by reference in their entirety.

FIELD OF THE INVENTION

This invention relates to liquid crystal displays comprising cells ofwell-defined shape, size and aspect ratio, which are filled with liquidcrystals, preferably with a guest dye, and novel processes for theirmanufacture.

BACKGROUND OF THE INVENTION

A polymer dispersed liquid crystal (PDLC) display usually comprises twotransparent plates with electrodes placed opposing each other, separatedby using spacers. A thin film of PDLC is enclosed between the twoplates. The PDLC film may be up to 200 micron thick, but usually havinga thickness of between 2 microns and 50 microns. The cell ishermetically sealed in order to eliminate oxygen and moisture, both ofwhich may chemically attack the liquid crystals. A thorough review ofthe PDLC technologies can be found in the book, “Liquid CrystalDispersions” by P. S. Drzaic (1995). Bistable displays of this typeusing cholesteric liquid crystals have also been taught in, for example,S. W. Stephenson, et al, SID'04 Digest, p. 774 (2004) and D.-K. Yang, etal, SID'03 Digest, p. 959 (2003).

A PDLC typically consists of micron-size droplets of alow-molecular-weight nematic liquid crystal dispersed in a polymerbinder. The nematic droplets strongly scatter light and the material hasa white opaque or translucent appearance (“off state”). When a voltagedifference is imposed between the two electrodes (“on state”), theelectric field aligns the droplets such that the ordinary refractiveindex of the liquid crystal nearly matches that of the isotropic polymermatrix, substantially reducing the scattering power of the droplets, andthus allowing light to transmit through. In the “on state”, the cellthus appears clear or transparent, in the “off state” it appears opaque.

In a guest-host PDLC display, a dye, particularly a pleochroic ordichroic dye, is added as a guest to the liquid crystal to produce ahigh color contrast display. For example, because the dye molecules havea property to orientate parallel to the liquid crystal molecules, if adichroic dye having a bar-shaped structure is added to the liquidcrystal, the direction of the dye molecules also changes if themolecular direction of the liquid crystal is changed by applying anelectric field on the opposing electrodes. Because this dye is madecolored or not depending on the orientation direction, it is possible toswitch between a colored state (“off state”) and a colorless state (“onstate”) by applying a voltage on the two electrodes. The use of dichroicor pleochroic dyes in guest-host PDLC displays to improve the contrastratio is well known in the art.

A PDLC display may be transmissive and/or reflective. A transmissivePDLC display has an internal illumination source. Imposing a voltage onthe two electrodes allows light to pass through the cell. A typicalexample of a transmissive PDLC display is a PDLC overhead projector.Reflective PDLC displays typically contain a reflective black or coloredfilter which becomes visible in the transparent state. Reflective PDLCdisplays may be found in PDA (personal digital assistant) devices.Transmissive and reflective PDLC displays are particularly attractivebecause polarizers are eliminated. Polarizers substantially reduce lightand decrease brightness of both direct view and projection displays. Theabsence of polarizers also gives a better viewing angle.

The PDLC displays prepared by prior art processes have manyshortcomings. For example, the polymer dispersed liquid crystalstypically have droplets of very broad particle size distribution, whichresults in significant hysteresis, higher operation voltage, poorcontrast ratio, undesirable red bleedthrough, and low level ofmultiplexing. However, the hysteresis of PDLC films must be low to showreproducible gray scales, and low voltage operation and high contrastratio of the device is essential for most PDA applications.Monodispersed liquid crystal particles in the micron size range havebeen taught in U.S. Pat. No. 5,835,174 (Clikeman, et al.), U.S. Pat. No.5,976,405 (Clikeman, et al.), and U.S. Pat. No. 6,037,058 (Clikeman, etal.) to reduce the hysteresis and operation voltage, and improve thelevel of multiplexity. The contrast ratio of PDLC device prepared fromthe monodispersed particles remains low for most applications. Toimprove the contrast ratio without trade off in the thickness of thePDLC film and operation voltage, guest dyes preferably, pleochroic dyesor dichroic dyes are needed. However, the prior art processes do notallow for the precise enclosure of a high concentration of guest dyes inthe liquid crystal phase during the manufacturing process, such thatonly a low concentration of dyes may be encapsulated in themonodispersed polymer particles. Some guest dyes may be left outside ofthe particles, thereby resulting in an increase in Dmin and a lowercontrast ratio.

It is highly desirable to create monodispersed liquid crystal domains,which would alleviate the requirement of high operation voltage, allowhigh contrast ratio and high level of multiplexing, and reducehysteresis.

SUMMARY OF THE INVENTION

The first aspect of the present invention is directed to a liquidcrystal (LC) display comprising cells of substantially uniform shape,size and aspect ratio. The cells are filled with LC preferably withguest dye(s).

Another aspect of the invention relates to a novel process for themanufacture of such a LC display.

A further aspect of the invention relates to the preparation of cells ofsubstantially uniform shape, size and aspect ratio. The cells enclose LCpreferably with guest dye(s) and are formed from microcups preparedaccording to the present invention. Briefly, the process for thepreparation of the microcups involves embossing a thermoplastic orthermoset precursor layer coated on a conductor film with apre-patterned male mold, followed by releasing the mold before, duringor after the thermoplastic or thermoset precursor layer is hardened byradiation, cooling, solvent evaporation, or other means. Alternatively,the microcups may be formed from imagewise exposure of the conductorfilm coated with a radiation curable layer followed by removing theunexposed areas after the exposed areas have become hardened.

Solvent-resistant, thermomechanically stable microcups havingsubstantially monodispersed size and shape can be prepared by either oneof the aforesaid methods. The size of microcups for most displayapplications is in the range of submicrons to 10 microns, morepreferably 0.5 microns to 5 microns. The shape may be any shape,although a shape allowing a higher total area of interface betweenliquid crystal and the microcups is preferred. The microcups are thenfilled with LC preferably with guest dye(s), and sealed.

Yet another aspect of the present invention relates to the sealing ofthe microcups filled with the LC, preferably with guest dye(s). Sealingcan be accomplished by a variety of ways. Preferably, it is accomplishedby dispersing into the LC phase before the filling step, a sealantcomposition containing a thermoplastic or thermoset precursor. Thesealant composition is immiscible with the LC and has a specific gravitylower than that of the LC. After filling, the thermoplastic or thermosetprecursor phase separates and forms a supernatant layer at the top ofthe LC. The sealing of the microcups is then conveniently accomplishedby hardening the precursor layer by solvent evaporation, interfacialreaction, moisture, heat, or radiation. UV radiation is the preferredmethod to seal the microcups, although a combination of two or morecuring mechanisms as described above may be used to increase thethroughput of sealing. Alternatively, the sealing can be accomplished byovercoating the LC with a sealant composition containing thethermoplastic or thermoset precursor. The solvent used in the sealantcomposition is critical. Preferably, it is immiscible with the LC andhas a specific gravity lower than that of the LC. It is also importantto control the surface tension and viscosity of the sealant compositionto ensure a good coating uniformity. The sealing is then accomplished byhardening the sealant composition by solvent evaporation, interfacialreaction, moisture, heat, radiation, or a combination of curingmechanisms. These sealing processes are also unique features of thepresent invention.

Yet another aspect of the present invention relates to the absence ofthe hysteresis of the LC displays. The LC displays of the presentinvention consist of substantially monodispersed microcups filled withliquid crystals and preferably a guest dye. The composition of themicrocups is optimized such that the isotropic refractive index of themicrocups is matched to the ordinary refractive index of the LC. In amanner similar to conventional PDLC displays, the LC displays of thepresent invention strongly scatter light in the absence of an electricfield (the “off state”). When a voltage difference is applied betweenthe two electrodes, the electric field aligns the LC which substantiallyreduces scattering power and allows light to transmit through the “onstate”. However, unlike the PDLC displays, the LC displays of thisinvention reach the maximum optically clear state at a much lowervoltage and, when the applied voltage is withdrawn, reverts back to theoriginal “off state” without undesirable hysteresis. The low operationvoltage, fast response time, and the absence of hysteresis of thedisplays of the present invention are critical for high quality displayapplications where low power consumption, reproducible gray scales andvideo rate are highly desirable.

Yet another aspect of the present invention relates to the manufactureof a LC display comprising stack of layers of microcups. The processingsteps include preparation of the first layer of microcups on a conductorsubstrate by anyone of the methods described above, filling themicrocups with a LC composition, sealing, and finally laminating thesealed microcups with a second conductor substrate precoated with anadhesive layer. The adhesives can be hot-melt, heat curable, moisturecurable, or radiation curable adhesives. Of particular interest, UVcurable adhesives are used in the present invention. To improve thecontrast ratio, more than one layer of the microcup array may be used.The processing steps include preparation of microcups, filling with theLC composition, sealing, overcoating or laminating the sealed microcuparray with a second layer of the microcup forming composition, formingthe second microcup array with any of the methods described previously,preferably by the embossing method, repeating several times the steps offilling and sealing of microcups, overcoating or laminating the sealedmicrocups with another layer of microcup forming composition, andfinally laminating the stack of microcup layers to a second conductorsubstrate precoated with an adhesive layer.

Yet another aspect of the present invention relates to a process for themanufacture of a full color reflective LC display by using a conductorsubstrate precoated with (R, G, B) color filters and preferably a blackmatrix. Alternatively a full color display can be prepared by laminatingthe preformed microcups with a layer of positively working photoresist,selectively opening a certain number of the microcups by imagewiseexposing the positive photoresist, followed by developing thephotoresist, filling the opened microcups with a LC compositioncontaining guest dye(s), preferably dichroic dyes of a first color, andsealing the filled microcups by a sealing process described previously.These steps may be repeated to create sealed microcups filled with LCcompositions containing guest dyes of a second or a third color. A blackbackground may be used to improve the contrast ratio and colorsaturation.

These multiple-step processes as disclosed may be carried outroll-to-roll continuously or semi-continuously. Consequently, they aresuitable for high volume and low cost production. These processes arealso efficient and inexpensive as compared to other processes for highvolume production operations. The LC display prepared according to thepresent invention is not sensitive to environment, particularly notsensitive to humidity and temperature. The display may be very thin,flexible, durable, easy-to-handle, and format-flexible. Since the LCdisplay prepared according to the present invention comprises cells offavorable aspect ratio and substantially monodispersed shape and size,the displays manufactured according to the present invention exhibitmany desirable properties such as low power consumption, fast responsetime, high level of multiplexing, high contrast ratio, and reproduciblegray scale presentation due to the absence of undesirable hysteresis.

Yet a further aspect of the present invention relates to a cholestericliquid crystal display. The microcups in such a cholesteric liquidcrystal display are filled with a cholesteric liquid crystalcomposition.

Yet still another aspect of the present invention relates to amicrocup-based liquid crystal display wherein the microcups are filledwith a liquid crystal composition comprising a chiral molecule.

BRIEF DESCRIPTION OF THE DRAWINGS

FIGS. 1 a and 1 b show the “off” and “on” states respectively of atypical PDLC device.

FIGS. 1 c, 1 d and 1 e are schematic depictions of the LC displays ofthe present invention.

FIGS. 2 a-2 d illustrate a typical method of preparing the male mold formicroembossing.

FIGS. 3 a-3 b show the roll to roll process for the manufacture of aLCD, in particular, the creation of microcups by embossing a conductorfilm coated with a UV curable composition.

FIGS. 4 a-4 b show two SEM micrographs of microcup arrays prepared bymicroembossing.

FIGS. 5 a 1, 5 a 2, 5 b 1, 5 b 2, 5 c 1, and 5 c 2 show alternativeprocessing steps for preparing the microcups involving imagewiseexposure of the conductor film coated with a radiation curable materialto UV radiation.

FIGS. 6 a-6 f show examples of different shapes and patterns of microcuparrays.

FIG. 7 is a flow chart for manufacturing a monochrome LCD.

FIGS. 8 a-8 h show a process for the manufacturing of a full colordisplay using three primary color guest dyes.

FIG. 9 a shows a typical hysteresis curve for a traditional PDLC device.

FIG. 9 b shows the absence of the hysteresis loop in a typical microcupLCD of this invention.

DETAILED DESCRIPTION OF THE INVENTION

Definitions

Unless defined otherwise in this specification, all technical terms areused herein according to their conventional definitions as they arecommonly used and understood by those of ordinary skill in the art.

The term “microcup” refers to the cup-like indentations created bymicroembossing or imagewise exposure.

The term “cell”, in the context of the present invention, is intended tomean the single unit formed from a sealed microcup. The cells are filledwith liquid crystals preferably with guest dye(s).

The term “well-defined”, when describing the microcups or cells, isintended to indicate that the microcup or cell has a definite shape,size and aspect ratio which are pre-determined according to the specificparameters of the manufacturing process.

The term “monodispersed”, when describing the microcups or cells, isintended to indicate that the microcup or cell has a narrow distributionof dimensions such as diameter, length, width, and height.

The term “aspect ratio” is a commonly known term in the art of PDLCdisplays. In this application, it refers to the depth to width or depthto length ratio of the microcups.

The sealing of display cells or microcups, in the context of the presentapplication, is accomplished by the “top-sealing” methods as describedherein in which the display cells or microcups are filled andtop-sealed, as opposed to the conventional edge sealing process. In theconventional edge sealing process, two electrode layers and an edge sealadhesive are required to enclose and edge-seal the liquid crystalcomposition within the cells(s). In contrast, in the top-sealingprocess, the liquid crystals are enclosed and top-sealed before anelectrode layer is disposed onto the display cell(s). Therefore, theterm “sealing layer” throughout this application may be replaced withthe term “top-sealing layer”.

Preferred Embodiments

A typical PDLC display, as shown in FIG. 1 a, comprises two electrodeplates (10, 11), at least one of which is transparent (10), and a layerof liquid crystal domains dispersed in an isotropic polymer matrix.

FIG. 1 a also shows the random direction of the liquid crystal moleculeswhen no voltage (13) is imposed on the two electric plates (10,11). Theincoming light (14) is thus scattered (15) by the random orientation ofthe liquid crystal molecules FIG. 1 b shows that the liquid crystalmolecules are lined up in a certain direction when voltage (13) isimposed on the two electric plates. Incoming light (16) thus istransmitted through (17) because the ordinary refractive index of theliquid crystal is matched to the isotropic refractive index of thepolymer matrix (12).

A monochrome liquid crystal display of the present invention,schematically shown in FIG. 1 c comprises well-defined cells (18)enclosed between the two electrodes (10, 11). The cells (18) are ofsubstantially uniform shape and size and are filled with a LCcomposition. The electrode on the viewer's side is transparent and atleast one of the two electrodes is patterned. A full range of color isobtained if three primary color filters (19), such as red (R), green(G), and blue (B), are used (FIG. 1 d).

Alternatively, a full color display of the present invention may beobtained by filling the well-defined cells (1, 2 and 3) with a LCcomposition containing R, G, and B guest dyes, preferably dichroic dyesrespectively. For example, the cells (1) are filled with LC with a redguest dye, adjacent cells (2) are filled with LC with a green guest dye,and adjacent cells (3) are filled with LC with a blue guest dye. Thenumber of layers of the cells containing LC may be more than one (FIG. 1e).

The process for the preparation of such LC displays involves severalaspects.

I. Preparation of the Microcups

(a) Preparation of the Male Mold

The male mold may be prepared by a photoresist process followed byeither etching or electroplating. A representative example for thepreparation of the male mold is given in FIGS. 2 a-2 d. Withelectroplating (FIG. 2 a), a glass base (20) is sputtered with a thinlayer (typically 3000 Å) of a seed metal (21) such as chrome inconel. Itis then coated with a layer of photoresist (22) and exposed to UV. Amask (24) is placed between the UV and the layer of photoresist (22).The exposed areas of the photoresist become hardened. The unexposedareas are then removed by washing them with an appropriate solvent. Theremaining hardened photoresist is dried and sputtered again with a thinlayer of seed metal. A master (FIG. 2 b) is then ready forelectroforming. A typical material used for electroforming is nickelcobalt (23). Alternatively, the master can be made of nickel by nickelsulfamate electroforming or electrodless nickel deposition as describedin “Continuous manufacturing of thin cover sheet optical media”, SPIEProc. Vol. 1663, p. 324 (1992). The floor of the mold (FIG. 2 d) istypically between 1 to 5 microns. The master can also be made usingother microengineering techniques including e-beam writing, dry etching,chemical etching, laser writing or laser interference as described in“Replication techniques for micro-optics”, SPIE Proc. Vol. 3099, pp.76-82 (1997). Alternatively, the mold can be made by photomachiningusing plastics, ceramics or metals.

(b) Preparation of the Microcups by Embossing

This processing step is shown in FIGS. 3 a and 3 b. The male mold (30)may be placed either above (FIG. 3 a) or below (FIG. 3 b) the web (34).The transparent conductive substrate is constructed by forming atransparent conductor film (31) on a glass plate or a plastic substrate.A layer of a thermoplastic or thermoset precursor (32) is then coated onthe conductor film. The thermoplastic or thermoset precursor layer isembossed at a temperature higher than the glass transition temperatureof the thermoplastic or thermoset precursor layer by the male mold inthe form of a roller, plate or belt.

The thermoplastic or thermoset precursor (32) for the preparation of themicrocups (33) may be multifunctional acrylate or methacrylate, vinylether, epoxide and their oligomers, polymers and the like.Multifunctional acrylate and its oligomers are the most preferred. Acombination of a multifunctional epoxide and a multifunctional acrylateis also very useful to achieve desirable physico-mechanical properties.A crosslinkable oligomer imparting flexibility, such as urethaneacrylate or polyester acrylate, is usually also added to improve theflexure resistance of the embossed microcups. The composition maycontain polymer, oligomer, monomer and additives or only oligomer,monomer and additives. The glass transition temperatures (or Tg) forthis class of materials usually range from about −70° C. to about 150°C., preferably from about −20° C. to about 50° C. The microembossingprocess is typically carried out at a temperature higher than the Tg. Aheated male mold or a heated housing substrate against which the moldpresses may be used to control the microembossing temperature andpressure.

As shown in FIGS. 3 a and 3 b, the mold is released during or after theprecursor layer is hardened to reveal an array of microcups (33). Thehardening of the precursor layer may be accomplished by cooling,cross-linking by radiation, heat or moisture. If the curing of theprecursor is accomplished by UV radiation, UV may radiate onto thetransparent conductor film from the bottom or the top of the web (34) asshown in the two figures. Alternatively, UV lamps may be placed insidethe mold. In this case, the mold must be transparent to allow the UVlight to radiate through the pre-patterned male mold on to the precursorlayer.

FIGS. 4 a and 4 b show SEM micrographs of two microcup arrays preparedby microembossing.

(c) Preparation of the Microcups by Imagewise Exposure

Alternatively, the microcups may be prepared by imagewise exposure (FIG.5 a) of a radiation curable material (51) coated on the conductor film(52) to UV or other forms of radiation through a mask (50). Theconductor film (52) is on a plastic substrate (53).

For a roll-to-roll process, the photomask may be synchronized with theweb and move at the same speed as the latter. In the photomask (50) inFIG. 5 a, the dark squares (54) represent the opaque area and the space(55) between the dark squares represents the opening area. The UVradiates through the opening area (55) onto the radiation curablematerial. The exposed areas become hardened and the unexposed areas(protected by the opaque area in the mask) are then removed by anappropriate solvent or developer to form the microcups (56). The solventor developer is selected from those commonly used for dissolving ordispersing the radiation curable materials such as methylethylketone,toluene, acetone, isopropanol or the like.

FIGS. 5 b and 5 c illustrate two other options for the preparation ofmicrocups by imagewise exposure. The features in these two figures areessentially the same as shown in FIG. 5 a and the corresponding partsare also numbered the same. In FIG. 5 b, the conductor film (52) used isopaque and pre-patterned. In this case, it may be advantageous toimagewise expose the radiation sensitive material through the conductorpattern, which serves as the photomask. The microcups (56) can then beformed by removing the unexposed areas after UV radiation. In FIG. 5 c,the conductor film (52) is also opaque and line-patterned. The radiationcurable material is exposed from the bottom through the conductor linepattern (52), which serves as the first photomask. A second exposure isperformed from the other side through the second photomask (50) having aline pattern perpendicular to the conductor lines. The unexposed area isthen removed by a solvent or developer to reveal the microcups (56).

In general, the microcups (56) can be of any shape to maximize the lightscattering effect of the liquid crystal domains. The microcups are ofsubstantially uniform size and shape in one system. However, microcupshaving different shapes and sizes may be used for different colors. Forexample, microcups filled with LC with a red guest dye may have adifferent shape or size from the green microcups or the blue microcups.Furthermore, a pixel may consist of different numbers of microcups ofdifferent colors. Also, a pixel may consist of a number of small greenmicrocups, a number of large red microcups, and a number of small bluemicrocups. It is not necessary to have the same shape and number for thethree colors. FIGS. 6 a-6 f illustrate six examples of microcup patternsthat may be used in the present invention.

The openings of the microcups may be round, square, rectangular,hexagonal, or any other shape. The partition area between the openingsis preferably kept small in order to achieve a high color saturation andcontrast ratio while maintaining desirable mechanical properties.

For LC displays of the present invention, the dimension of eachindividual microcup may be in the range of about 0.04 to about 100 μm²,preferably from about 0.6 μm² to about 36 μm². The depth of themicrocups is in the range of about 1 to about 10 microns, preferablyfrom about 2 to about 6 microns. The opening to wall ratio is in therange of from about 0.05 to about 20, preferably from about 0.2 to about10. The distances of the openings usually are in the range of about 0.5to about 6 microns preferably from about 1 to about 4 microns, from edgeto edge of the openings.

II. Liquid Crystals, Dichroic Dyes and Their Mixtures

The thus-formed array of microcups is filled with liquid crystals,usually by a coating process. Liquid crystals may also contain adichroic dye to impart a monochrome color to the display and to increasethe contrast.

Liquid crystal materials that may be used in the present invention arewell known in the art. Examples of liquid crystal materials that may beused in the present invention include, but not limited to, E7, TL205,TL213, BL006, BL009 and BL037 from E. Merck Co. (Germany). Other liquidcrystal materials are also listed in U.S. Pat. No. 5,835,174 (Clikeman,et al.).

Liquid crystals in the present invention are preferred to contain guestdye(s). Guest dyes of the present invention are dichroic and are wellknown in the art. U.S. Pat. No. 5,589,100 (Grasso, et al) states thatarylazo or poly(arylazo) dichroic dyes may be used with liquid crystalas well as lists other dichroic dyes suitable for the present invention.

The incorporation of dyes not only adds color but also can substantiallyimprove contrast in some display applications. To be suitable, dyes musthave high order parameters and proper solubility in the host liquidcrystal material. High order parameter is promoted by dyes withelongated shape having a large ratio of molecular length to width,similar to the shape of the molecules of liquid crystal host material.The LC with guest dye(s) should provide good viewing characteristics,such as high contrast, high extinction, and chemical and photochemicalstability. Example of dichroic dyes having a high dichroic ratio used inthe present invention include the Blue AB2, Red AR1 and Yellow AG1 fromFunktionfluid Gmb (Germany) and SI-486 (yellow), SI426 (red), M483(blue), S344 (black), S428 (black) and S7 (black) from Mitsui Toatsu.

Nonionic azo and anthraquinone dyes are also useful. Examples include,but are not limited to: Oil Red EGN, Sudan Red, Sudan Blue, Oil Blue,Macrolex Blue, Solvent Blue 35, Pylam Spirit Black and Fast Spirit Blackfrom Pylam Products Co., Arizona, Sudan Black B from Aldrich,Thermoplastic Black X-70 from BASF, anthraquinone blue, anthraquinoneyellow 114, anthraquinone red 111, 135, anthraquinone green 28 fromAldrich. In any case, the dye must be chemically stable and should havea low solubility in the microcup material. Liquid crystals or dyesshould not at any time attack the microcups.

Cholesteric liquid crystals may also be used in some applications. Thecholesteric phase is a liquid crystal phase exhibited by chiralmolecules or mixtures containing chiral components. Chiral molecules donot have reflection symmetry. A cholesteric liquid crystal is similar toa nematic liquid crystal; it has long-range orientational order but nolong-range positional order. It has, however, one property that isdifferent from the nematic liquid crystal, in that it has a helicalstructure. In a plane perpendicular to the helical axis, the liquidcrystal directors on two neighboring planes are twisted slightly withrespect to one another. Cholesteric liquid crystals exhibit two stablestates at zero field: the reflecting planar texture and thenon-reflecting (scattering) focal conic texture. Their opticalproperties, such as color and reflectivity, are important in displayapplications. Detailed information on cholesteric liquid crystals may befound in “Reflective Liquid Crystal Displays” by Shin-Tson Wu andDeng-Ke Yang, John Wiley & Sons Ltd., (2001); “Liquid CrystalDispersions” by Paul Drzaic, World Scientific Publishing Co., (1995);“Polymers, Liquid Crystals, and Low Dimensional Solids” ed. by N. Marchand M. Tosi, Plenum Press (1984); and “Polymer Liquid Crystals” ed. byA. Ciferri, W. R. Krigbaum and R. B. Meyer, Academic Press, Inc.,(1982), the contents of all of which are incorporated herein byreference in their entirety.

The cholesteric phase is a spontaneously twisted analog of the nematicphase. Most of the important cholesteric materials are simply chiralanalogs of nematogens in which the chirality being introduced by havinga chiral center in a terminally situated alkyl or alkoxy group. Amicrocup-based liquid crystal display may be achieved by filling themicrocups with a liquid crystal composition comprising a chiralmaterial.

Typical chiral nematic (cholesteric) and chiral smetic materials aremixtures of various components, consisting of both chiral and non-chiralcomponents. Suitable nematic liquid crystals may include, but are notlimited to, E7, E48, E31 and E80 from E. Merck, ZOC-1020XX (Chisso Co.)and other cyanobiphenyl liquid crystals. Suitable chiral materialsuseful in the present invention may include, but are not limited to,cholesteryl alkyl carbonate, cholesteryl alkenyl carbonate or aderivative thereof such as cholesteryl oleyl carbonate, CB15, ZLI-4571,ZLI-811, CE2, TM74A (all from E. Merck), CM-33 (Chisso Co.), TADDOL[5-((4R,5R)-2,2-dimethyl-α, α, α′,α′-tetra(phenanthren-9-yl)-1,3-di-oxolane-4,5-dimethanol],(S)-(+)-(9-anthryl)-2,2,2-trifluoroethanol (Aldrich) and DASE 1835 [asdisclosed in “LP-4: Late-News Poster: Chiral Dopants for LCDApplications” by F. Kuschel, C. Boeffel and M. Bauer, SID 02 Digest,P-554, the content of which is incorporated herein by reference in itsentirety] and a mixture thereof. Cholesteric liquid crystal mixturessuitable for this invention may include, but are not limited to, CB 15,CE2 from VWR International Limited (formerly BDH Chemicals), BL118 (fromMerck) and the liquid crystal mixture consisting of BL061, E454 and C6(e.g., 75.6% BL061, 23.9% E454 and 0.5% C6) from E. Merck, a mixtureconsisting of E-31 LV,4″-(2-methylbutylphenyl)-4′-(2-methylbutyl)-4-biphenyl carboxylate and4-cyano-4′-(2-methyl)butylbiphenyl [e.g., 50-70% Merck E-31LV, 15-25%4″-(2-methylbutylphenyl)-4′-(2-methylbutyl)-4-biphenyl carboxylate(chiral material) and 15-25% 4-cyano-4′-(2-methyl)butylbiphenyl (chiralmaterial)]. A list of liquid crystal materials and mixtures thereofsuitable for providing the cholesteric mesophase may be found in, forexample, U.S. Pat. Nos. 3,704,056, 3,680,950, 4,097,127, 5,384,067,5,453,863 and 6,532,052, and “Polymer Liquid Crystals” by A. Ciferri, W.R. Krigbaum and R. B. Meyer, ed., Academic Press, Inc., (1982).Preferably the cholesteric liquid crystal mixture comprises from about20 to about 60% by weight of a chiral material.

Other additives such as silica or pigments or dyes, particularlydichroic dyes may also be added to enhance the stability of the liquidcrystal texture or adjust the color.

Before the filling and sealing of the liquid crystal composition in themicrocups, the surface may be precoated or pretreated with an alignmentlayer.

The alignment layer may be deposited on a substrate. If a conductorlayer is present, the alignment layer is coated or deposited onto theconductor side on the substrate. The alignment layer may be the same asthose typically used in LCD manufacturing such as a polyimide, asurfactant, a coupling agent or a photoalignment polymer or oligomer.After deposition and baking, the alignment layer may be aligned byrubbing or exposure to a polarized light. In some applications, adiamond turn may be used to create microgrooves or grating structuresfor the LC alignment.

In general, the photoalignment polymers or oligomers may have aphotoalignment functional group on the main chain or a side chain. Theprecursors of the photoalignment polymers and copolymers having aphotoalignable functional group on the main chain or a side chain mayalso be useful. The functional groups may include, but are not limitedto, cinnamate, coumarin, chalcony, benzolidenenaphthalidine,benzaylideneacetophenone, diphenylacetylene, stilbazole, stilbene,diphenylacetylene, diazo, spiropyran and the like.

The sealing layer formed according to Section III below may also serveas an alignment layer, the details of which are disclosed in aco-pending application, U.S. Ser. No. 10/771,848, filed Feb. 4, 2004,the content of which is incorporated herein by reference in itsentirety.

III. Sealing of the Microcups

The sealing of the microcups may be accomplished in a number of ways. Apreferred approach is to disperse a UV curable sealant composition intothe LC composition. The UV curable composition is immiscible with andhas a specific gravity lower than that of the LC. The UV curablecomposition and the LC composition, are thoroughly blended in an in-linemixer and immediately coated onto the microcups with a precision coatingmechanism such as Myrad bar, gravure, doctor blade, slot coating or slitcoating. Volatile solvents may be used to control the viscosity, thecoverage of the coating, and facilitate the phase separation of thesealant phase from the LC phase. Excess fluid may be scraped away by awiper blade or a similar device. The thus-filled microcups are thendried and the UV curable composition floats to the top of the LC. Themicrocups may be sealed by curing the supernatant UV curable layerduring or after it floats to the top. UV or other forms of radiationsuch as visible light, IR and electron beam may be used to cure and sealthe microcups. Alternatively, heat or moisture, or the combination mayalso be employed to cure and seal the microcups, when heat or moisturecurable sealant compositions are used.

Surfactants may be used to improve the adhesion of the sealant to themicrocup wall and the wetting at the interface between the LC and thesealing materials. Useful surfactants include the FC surfactants from 3MCompany, Zonyl fluorosurfactants from DuPont, fluoroacrylates,fluoromethacrylates, fluoro-substituted long chain alcohols,perfluoro-substituted long chain carboxylic acids and their derivatives,and Silwet surfactants from OSi.

Alternatively, the LC and the sealant composition may be coatedsequentially into the microcups. Thus, the sealing of the microcups maybe accomplished by overcoating a thin layer of a thermoplastic orthermoset precursor composition which is curable by radiation, heat,moisture or interfacial reactions and curing on the surface of thefilled microcups. Interfacial polymerization followed by UV curing isvery beneficial to the sealing process. Intermixing between the LC layerand the overcoat can be significantly suppressed by the formation of athin barrier layer at the interface by interfacial polymerization. Thesealing is then completed by a post curing step, preferably by UVradiation. To further reduce the degree of intermixing, it is highlydesirable that the specific gravity of the overcoating is lower thanthat of the LC. Volatile organic solvents may be used to adjust theviscosity and the thickness of the coatings. When a volatile solvent isused in the overcoat, it is preferred that it is immiscible with the LCor the dye and has a specific gravity lower than that of the LC phase.The two-step overcoating process is particularly useful when the dyeused is at least partially soluble in the sealant layer. To furtherreduce the degree of intermixing between the sealant layer and the LCphase, the filled microcup array may be chilled before overcoating ofthe sealant layer.

Alternatively, sealing of the filled microcups may be achieved bytransfer laminating an adhesive layer from a release substrate onto thefilled microcups, preferably followed by hardening the adhesive layer byheat, radiation or by simple solvent evaporation, and finally peelingoff the release substrate. Chilling of the filled microcups is alsobeneficial to the sealing by transfer lamination process.

The top sealing layer may be formed of a photo alignable material. Inthis case, the top sealing layer may be photo aligned by a polarizedlight, such as UV light.

IV. Preparation of Monochrome LC Displays

The process is illustrated by the flow diagram as shown in FIG. 7. Allmicrocups are filled with LC containing the same color guest dye(s). Theprocess can be a continuous roll-to-roll process comprising thefollowing steps:

-   1. Coat a layer of thermoplastic or thermoset precursor (70)    optionally with a solvent onto a transparent conductor film (71).    The solvent, if present, readily evaporates.-   2. Emboss the thermoplastic or thermoset precursor layer at a    temperature higher than the glass transition temperature of the    thermoplastic or thermoset precursor layer by a pre-patterned male    mold (72).-   3. Release the mold from the thermoplastic or thermoset precursor    layer preferably during or after it is hardened by proper means.-   4. Fill in the thus-formed array of microcups (73) with a LC    composition (74) containing a thermoplastic or thermoset precursor    composition, which is incompatible with the LC and has a lower    specific gravity than the LC phase.-   5. Seal the microcups by hardening the thermoplastic or thermoset    precursor preferably by solvent evaporation, radiation such as UV    (75), or by heat or moisture during or after the thermoplastic or    thermoset precursor separates and forms a supernatant layer on top    of the LC phase, thus forming closed LC cells containing LC and    preferably guest dye(s).-   6. Laminate the sealed array of LC cells with a second conductor    film (76) pre-coated with an adhesive layer (77) which may be a    pressure sensitive adhesive, a hot melt adhesive, a heat, moisture,    or radiation curable adhesive.

The laminate adhesive may be hardened by heat or radiation such as UV(78) through the top conductor film if the latter is transparent to theradiation. The laminated product may be cut (79) to appropriate size fordevice assembling.

The preparation of the microcups described above can be convenientlyreplaced by the alternative procedure of imagewise exposing theconductor film coated with a radiation curable material followed byremoving the unexposed areas by an appropriate solvent. The sealing ofthe microcups may alternatively be accomplished by the overcoating ortransfer lamination processes described previously, followed byhardening the sealant over the surface of the filled microcups.

To improve the contrast ratio, more than a layer of the microcup arraycan be used (FIG. 1 c). Thus, after hardening the sealant layer on thefilled microcups (the Step 5), another layer of microcup formingcomposition is coated onto the sealed microcup array. The Steps 2-5 canbe repeated several times until an appropriate contrast ratio isachieved. The multilayer microcup stack is then laminated with a secondconductor layer, and cut to appropriate size for display assembly. It isimportant to note that at least one of the two conductor films isprepatterned. Also at least the conductor film at the viewer's side istransparent.

V. Preparation of Multi-Color LC displays

A multi-color LC display of the present invention can be prepared byusing (R, G, B) color filters and a black matrix underneath themonochrome display prepared in the previous section (FIG. 1 d).Alternatively a full color display of the present invention can beprepared by filling microcups with LC containing guest dye(s) ofdifferent colors (FIG. 1 e). In addition to processes described in thepreparation of monochrome displays, additional steps are required forsuch a color display. These additional steps include (1) laminating thealready formed microcups with a positively working dry-film photoresistconsisting of at least a removable support such as PET-4851 fromSaint-Gobain, Worcester, Mass., a novolac positive photoresist such asMicroposit S1818 from Shipley, and an alkali-developable adhesive layersuch as a mixture of Nacor 72-8685 from National Starch and Carboset 515from BF Goodrich; (2) selectively opening a certain amount of themicrocups by imagewise exposing the photoresist, removing the removablesupport film, and developing the positive photoresist with a developersuch as diluted Microposit 351 developer from Shipley; (3) filling theopened microcups with the LC with guest dye(s) of a first primary color;and (4) sealing the filled microcups as described in the preparation ofmonochrome displays. These additional steps may be repeated to createmicrocups filled with LC of second and third primary colors.

More specifically, a multi-color LC display may be prepared according tothe steps as shown in FIG. 8:

-   1. Coat a layer of a thermoplastic or thermoset precursor (80) on a    conductor film (81).-   2. Emboss the thermoplastic or thermoset precursor layer at a    temperature higher than its glass transition temperature by a    pre-patterned male mold (not shown).-   3. Release the mold from the thermoplastic or thermoset precursor    layer preferably during or after it is hardened by solvent    evaporation, cooling, or crosslinking by radiation, heat or    moisture.-   4. Laminate the thus formed array of microcups (82) with a positive    dry-film photoresist, which comprises at least a positive    photoresist (84) and a removable plastic cover sheet (not shown).    The positive dry film photoresist may comprise an adhesive layer    (83) to improve the adhesion between the microcups and the    photoresist.-   5. Imagewise expose (FIG. 8 c) the positive photoresist by UV,    visible light, or other radiation, remove the cover sheet, develop    and open microcups in the exposed area. The purpose of Steps 4 and 5    is to selectively open the microcups in a predetermined area (FIG. 8    d).-   6. Fill in the opened microcups with a LC composition containing    guest dye(s) (85) of a first primary color and a sealant composition    (86), which is incompatible with the LC phase and has a lower    specific gravity than the LC phase.-   7. Seal the microcups to form closed LC cells containing LC with    guest dye(s) of the first primary color by hardening the sealant    layer by solvent evaporation or curing preferably by radiation such    as UV, less preferably by heat or moisture during or after the    sealant separates and forms a supernatant layer on top of the liquid    crystal phase (FIG. 8 e).-   8. Steps 5-7 described above may be repeated to generate    well-defined cells containing LC with guest dye(s) of different    colors in different areas (FIGS. 8 e, 8 f and 8 g).-   9. Laminate the sealed array of LC cells to a second transparent    conductor film (87) pre-coated with an adhesive layer (88) which may    be a pressure sensitive adhesive, a hot melt adhesive, a heat,    moisture, or radiation curable adhesive.-   10. Harden the adhesive.

The preparation of the microcups described in the process above canconveniently be replaced by the alternative procedure of imagewiseexposing the conductor film coated with a radiation curable materialfollowed by removing the unexposed areas by an appropriate solvent. Thesealing of the microcups may be alternatively accomplished by directlycoating a layer of the thermoplastic or thermoset precursor materialover the surface of the liquid phase.

The thickness of the display produced by the present processes asdescribed can be as thin as a piece of paper. The width of the displayis the width of the coating web (typically 3-90 inches). The length ofthe display can be anywhere from inches to thousands of feet dependingon the size of the roll.

EXAMPLES

The following examples are given to enable those skilled in the art tomore clearly understand and to practice the present invention. Theyshould not be considered as limiting the scope of the invention, butmerely as being illustrative and representative thereof.

Example 1 Preparation of Microcups by Microembossing

The composition shown in Table 1 was coated with a Myrad bar #6 coatedonto a 2 mil PET film precoated with an ITO conductor layer fromSheldahl (Northfield, Minn.). A pre-patterned (4×4×4 microns) cobaltnickel male mold and a mold release Frekote 700-NC from Henkel were usedfor microembossing. The coating thickness was controlled to be about 5microns. The coated film was then embossed by the stencil using apressure roller at 90° C. The coating was then UV-cured for about 1minute through the Mylar film using a Cure Zone exposure unit (ADACTechnologies) equipped with a metal fluoride lamp with an intensity of80 mW/cm² at 365 nm. The embossed film was then released from the moldto reveal well-defined (4×4×4 microns) microcups. The microembossing wascarried out using the GBC Laminator at 90° C. TABLE 1 UV-curableAcrylate Formulation for Microcups No. Description Ingredient SupplierParts 1 Epoxy Ebecryl 600 UCB Chemicals 55 acrylate 2 Polyester Ebecryl830 UCB Chemicals 15 acrylate 3 Urethane Ebecryl 6700 UCB Chemicals 10acrylate 4 Silicon Ebecryl 350 UCB Chemicals 5 Acrylate 5 MonomerSartomer SR238 Sartomer 10 6 Monomer Sartomer SR306 Sartomer 5 7 MonomerSartomer SR351 Sartomer 5 8 Photo- Irgacure 500 Ciba 1 initiator 9Synergist Methyl diethanol amine Aldrich 0.5 10 Solvent MEK Aldrich 100

Example 2 Preparation of Microcups by Microembossing

The same as Example 1 except the formulation shown in Table 2 was coatedand embossed with a male mold of 4×4×4 microns. TABLE 2 UV-curableAcrylate Formulation for Microcups No. Description Ingredient SupplierParts 1 Epoxy acrylate Ebecryl 600 UCB Chemicals 50 2 Polyester acrylateEbecryl 830 UCB Chemicals 15 3 Urethane acrylate Ebecryl 6700 UCBChemicals 10 4 Silicon acrylate Ebecryl 350 UCB Chemicals 5 5 MonomerPoly Aldrich 5 (ethylene glycol) methacrylate 6 Monomer Sartomer SR238Sartomer 5 7 Monomer Sartomer SR306 Sartomer 5 8 Monomer Sartomer SR351Sartomer 5 9 Photoinitiator Irgacure 907 Ciba 0.5 10 Solvent MEK Aldrich300

Example 3 Preparation of Microcups by Microembossing

The composition shown in Table 3 was laminated using a pressure rollerbetween a 2 PET film precoated with an ITO conductor layer, and apre-patterned (4×4×4 microns) cobalt nickel mold. The PET/ITO film wastreated with a corona discharge (Electro-Technic Products, Model BD-10A,Chicago, Ill.) for 5 sec. The cobalt nickel mold was pretreated with amold release Frekote 750-NC. The coating was then UV cured for 1 minthrough the PET/ITO film. The embossing film was then released from themold to reveal well-defined (4×4×4 microns) microcups with a thicknessof 5.5 microns as measured by a Mituyoto thickness gauge. TABLE 3UV-curable Acrylate Formulation for Microcups No. Description IngredientSupplier Parts 1 Epoxy acrylate Ebecryl 600 UCB Chemicals 40 2 Polyesteracrylate Ebecryl 830 UCB Chemicals 15 3 Urethane acrylate Ebecryl 6700UCB Chemicals 10 4 Silicon acrylate Ebecryl 350 UCB Chemicals 5 5Monomer Poly Aldrich 15 (ethylene glycol) methacrylate 6 MonomerSartomer SR238 Sartomer 5 7 Monomer Sartomer SR306 Sartomer 5 8 MonomerSartomer SR351 Sartomer 5 9 Photoinitiator Irgacure 907 Ciba 0.5

Example 4 Preparation of Filled Microcups with Liquid Crystal Solution

The microcups generated in Example 3 were washed with hexanes, then withMEK, and oven dried (66° C.) for 10 min. A liquid crystal BL006 (E.Merck Co., Germany) solution containing 1 wt % Silwet L7608 (OSiSpecialties) was mixed with 9 times volume of MPK, and the resultingsolution was coated on microcup using Myrad bar #16. Excess solvent inthe microcup was evaporated in oven (66° C.) for 10 min.

Example 5 Preparation of Filled Microcups with Liquid Crystal SolutionContaining Blue Dichroic Dye

The microcups generated in Example 3 were washed with hexanes, then withMEK, and oven dried (66° C.) for 10 min. A liquid crystal BL006 (E.Merck Co., Germany) solution containing 3 wt % dichroic dye Blue AB2(Funktionfluid Gmb, Germany) and lwt % Silwet L7608 (OSi Specialties)was mixed with 9 times volume of MPK, and the resulting solution wascoated on microcup using Myrad bar #16. Excess solvent on the microcupwas evaporated in oven (66° C.) for 10 min.

Example 6 Preparation of Filled Microcups with Liquid Crystal SolutionContaining Black Dichroic Dye Mixture

The microcups generated in Example 3 were washed with hexanes, then withMEK, and oven dried (66° C.) for 10 min. A black dichroic dye mixturewas prepared by mixing three dichroic dyes Blue AB2, Red AR1, and YellowAG1 (Funktionfluid Gmb, Germany), together a liquid crystal BL006 (E.Merck Co., Germany) solution containing 2 wt % black dichroic dyemixture and 1 wt % Silwet L7608 (OSi Specialties) was mixed with 9 timesvolume of MPK, and the resulting solution was coated on microcup usingMyrad bar #16. Excess solvent on the microcup was evaporated in oven(66° C.) for 10 min.

Example 7 Sealing the Microcups by a Two-step (Overcoating) Process

A 10% solution of Vistalon 0106 (Exxon Mobil Chemicals) in Isopar E(Exxon Chemical) was coated onto a BL006-filled microcup sample preparedin Example 4, 5 or 6. The coating layer was uniform and transparent. Byusing a #3 Myrad bar, a sealing polymer layer with the weight coverageof 0.39 mg/in² was obtained and the thickness of the sealing polymerlayer was estimated to be 0.7μ. By using a #8 Myrad bar, a sealingpolymer layer with the weight coverage of 0.75 mg/in² was obtained andthe thickness of the sealing polymer layer was estimated to be 1.3μ. Thedensity of Vistalon 0106 was about 0.9 g/cm³.

Example 8 Sealing the Microcups by a Two-step (Overcoating) Process

Following the same procedure of Example 7, the microcups were sealed bycoating a 10% solution of a carboxylated acrylic copolymer, Amphomer28-4910 (National Starch) in 2-propanol onto the BL006-filled microcupsas prepared in Example 5. The coating layer was uniform and transparent.By using a #3 Myrad bar, a sealing polymer layer with the weightcoverage of 0.44 mg/in² was obtained and the thickness of the sealingpolymer layer was estimated to be 0.6μ. By using a #8 Myrad bar, asealing polymer layer with the weight coverage of 1.0 mg/in² wasobtained and the thickness of the sealing polymer layer was estimated tobe 1.3μ. The density of Amphomer 28-4910 was about 1.2 g/cm³.

Example 9 Traditional Polymerization Induced Phase Separation PDLCDisplay

For comparison, a traditional polymerization induced phase separationpolymer dispersed liquid crystal display was prepared. Different ratioof liquid crystal E7 (E. Merck, Germany) to Norland 65 (Norland) weremixed and sandwiched between two ITO coated glasses with a spacer ofeither 4.5 μm, 25 μm or 50 μm. Step wedge was used to optimize theUV-curing time under Cure Zone exposure unit (ADAC Technologies). FIG. 8a shows a typical hysteresis curve for polymerization induced phaseseparation PDLC prepared with the above procedure.

Example 10 SiPix Hysteresis-Free Liquid Crystal Display

A single layer liquid crystal display was assembled using microcupprepared in example 1, 2 or 3. Liquid crystal with or without dichroicdye(s) was filled into microcup with procedure described in example 4, 5or 6. These LC-filled microcups were then sealed with proceduredescribed in example 7 or 8. No hysteresis was observed for liquidcrystal displays made according to the present invention. (See FIG. 8b).

Example 11 Assembling of a Multilayer Display and it's Performance

Multilayer liquid crystal display was assembled to improve displayperformance. Single layer liquid crystal display was made as describedin example 10. Same procedure was used to emboss a second layer ofmicrocup on top of the first LC display, to fill LC with or without dyeand to seal the second layer of LC display. The registration of secondlayer microcup on the first layer was set to be off from the first layerabout 0 to 10 degree to maximize light scattering. Laminate twodouble-layer arrays to stack up a four-layer liquid crystal display. Ahigh contrast display was obtained with rising and falling response timeof 1 msec and ˜10 msec (at 40 volts) respectively. No hysteresis loopwas observed.

1. A liquid crystal display comprising a layer of display cells whereinsaid display cells are filled with a liquid crystal compositioncomprising a chiral material and sealed with a sealing layer formed froma sealing composition having a specific gravity lower than that of theliquid crystal composition.
 2. The liquid crystal display of claim 1wherein said chiral material is a chiral liquid crystal.
 3. The liquidcrystal display of claim 2 wherein said chiral liquid crystal is acholesteric liquid crystal.
 4. The liquid crystal display of claim 2wherein said chiral liquid crystal is CB15, CE2, TM74A, BL118 orcyanobiphenyl liquid crystals comprising a chiral side chain.
 5. Theliquid crystal display of claim 2 wherein said chiral liquid crystal isa mixture of BL061, E454 and C6.
 6. The liquid crystal display of claim2 wherein said chiral liquid crystal is a mixture of E31LV,4″-(2-methylbutylphenyl)-4′-(2-methylbutyl)-4-biphenyl carboxylate and4-cyano-4′-(2-methyl)butylbiphenyl.
 7. The liquid crystal display ofclaim 1 wherein said liquid crystal composition further comprising oneor more of the following: a) non-chiral liquid crystals; b) a chiraladditive; or c) a non-chiral additive.
 8. The liquid crystal display ofclaim 7 wherein said liquid crystal composition comprises about 20 toabout 60% by weight of a chiral material.
 9. The liquid crystal displayof claim 7 wherein said non-chiral liquid crystals are nemetic or smeticliquid crystals.
 10. The liquid crystal display of claim 7 wherein saidchiral additive is cholesteryl alkyl carbonate, cholesteryl alkenylcarbonate or a derivative thereof.
 11. The liquid crystal display ofclaim 7 wherein said non-chiral additive is a filler, a pigment or adye.
 12. The liquid crystal display of claim 11 wherein said filler issilica.
 13. The liquid crystal display of claim 12 wherein said silicais nano silica particles.
 14. The liquid crystal display of claim 11wherein said dye is a dichroic dye.
 15. The liquid crystal display ofclaim 1 further comprising an alignment layer between the layer ofdisplay cells and the liquid crystal composition.
 16. The liquid crystaldisplay of claim 15 wherein the alignment layer is aligned before thethe display cells are filled with the liquid crystal composition. 17.The liquid crystal display of claim 15 wherein the the alignment layeris photoaligned by a polarized light after the display cells are filledand sealed.
 18. The liquid crystal display of claim 1 wherein saidsealing layer also serves as an alignment layer.
 19. The liquid crystaldisplay of claim 18 wherein the sealing layer is photoaligned by apolarized light.
 20. The liquid crystal display of claim 1 wherein saiddisplay cells are formed from the microcup technology.
 21. The liquidcrystal display of claim 1 wherein said display cells are substantiallyuniform in size and shape.
 22. The liquid crystal display of claim 1wherein said display cells are non-spherical.
 23. The liquid crystaldisplay of claim 1 wherein said display cells have an opening arearanging from about 0.04 to about 100 μm².
 24. The liquid crystal displayof claim 23 wherein said display cells have an opening area ranging fromabout 1 to about 25 μm².
 25. The liquid crystal display of claim 1wherein said display cells have an opening having a circular, polygonal,hexagonal, rectangular or square shape.
 26. The liquid crystal displayof claim 1 wherein said display cells have a depth in the range fromabout 0.5 to about 10 microns.
 27. The liquid crystal display of claim26 wherein said display cells have a depth in the range from about 2 toabout 6 microns.
 28. The liquid crystal display of claim 1 wherein saiddisplay cells have an opening to wall ratio in the range from about 0.05to about
 20. 29. The liquid crystal display of claim 28 wherein saiddisplay cells have an opening to wall ratio in the range from about 0.2to about
 9. 30. The liquid crystal display of claim 11 wherein said dyeis a subtractive or additive color system.
 31. The liquid crystaldisplay of claim 1 wherein the display is multi-color and wherein colorfilters are laminated or coated onto the display.
 32. The liquid crystaldisplay of claim 31 wherein said filters are red, green, and blue colorfilters.
 33. The liquid crystal display of claim 1 wherein said liquidcrystal composition is partially filled in each of said display cells.34. The liquid crystal display of claim 33 wherein said partially filledliquid crystal composition is in contact with said sealing layer. 35.The liquid crystal display of claim 1 wherein said sealing compositioncomprises a thermoplastic or thermoset precursor.
 36. The liquid crystaldisplay of claim 1 wherein said sealing composition is a UV curablecomposition.